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Beilstein J. Org. Chem. 2007, 3, No. 39, doi:10.1186/1860-5397-3-39
Graphical Abstract
Scheme 1: General strategy for the synthesis of heterocycles via 5-endo-trig cyclisation
Scheme 2: Retrosynthesis of (+)-monomorine I
Scheme 3: The sulfone-mediated synthesis of 2,5-syn disubstituted pyrrolidines via a 5-endo-trig cyclisation
Scheme 4: The deprotection of N-benzoylpyrrolidines
Scheme 5: Synthesis of N-benzoyl protected pyrrolidine required for the preparation of (+)-monomorine I
Scheme 6: Mercury-mediated hydroamination
Scheme 7: Proposed transition state for mercury-mediate hydroamination
Scheme 8: Model study for the reductive amination-based cyclisation
Scheme 9: The synthesis of (+)-monomorine I